ISO 20950-1:2018

Water quality — Determination of available weak and dissociable (WAD) cyanide — Part 1: Method using ligand exchange, flow injection analysis (FIA), gas-diffusion and amperometric detection

Water quality — Determination of available weak and dissociable (WAD) cyanide — Part 1: Method using ligand exchange, flow injection analysis (FIA), gas-diffusion and amperometric detection

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Referenced standards

ASTM D6888-16ASTM D7728-11ISO 17690:2015ISO 2080:2008ISO 3696:1987ISO 5667-3:2012ISO 5725-2:1994ISO 8466-1:1990ISO 8466-2:2001ISO/TR 19588:2017
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ISO 20950-1:2018

Water quality — Determination of available weak and dissociable (WAD) cyanide — Part 1: Method using ligand exchange, flow injection analysis (FIA), gas-diffusion and amperometric detection

Water quality — Determination of available weak and dissociable (WAD) cyanide — Part 1: Method using ligand exchange, flow injection analysis (FIA), gas-diffusion and amperometric detection

This document specifies operationally defined methods for the determination of available WAD cyanide in various types of water such as drinking, ground, and surface, waters, and metallurgical processing tailings reclaim, heap leach barren, mill slurry tailings and leaching solutions, with cyanide concentrations from 5 μg/l to 2 000 mg/l expressed as cyanide ions in the undiluted sample. The range of application can be changed by varying the operation conditions, e.g. by using a different injection volume, thicker membrane, detector response, etc.

NOTE ISO 2080:2008, 3.105, defines free cyanide. The concentration of available WAD cyanide includes free cyanide and some of the metals complexed in solution as determined by a specified analytical method but not all of the metal complexes present in total cyanide (3,191).

In this method, six suitable mass concentration ranges from 5 μg/l to 50 μg/l, from 50 μg/l to 500 μg/l, from 0,5 mg/l to 5 mg/l, from 5 mg/l to 50 mg/l, from 50 mg/l to 500 mg/l and from 500 mg/l to 2 000 mg/l are described.

Edition2018
Standard Part No1
Published Date2018
Published ByInternational Standardization Organisation
Page Count17